摘要
Pure organic room-temperature phosphorescence(RTP)materials have attracted wide attention owing to their excellent luminescent properties and great potential in various applications.In this work,iminostilbene and its analogues are applied to realize RTP emission by copolymerizing with acrylamide.It can be concluded that the growth of alkane chain in monomers can enhance the lifetime and photoluminescence quantum yield of RTP emission,and polymers with the larger conjugated structure of the monomer show a longer RTP emission wavelength.This work provides a series of new pure organic RTP materials and might provide new thoughts for designing more advanced and superior RTP materials.
基金
the financial support from the National Natural Science Foundation of China (Nos. 21788102, 22125803, 22020102006 and 21871083)
Program of Shanghai Academic/Technology Research Leader (No. 20XD1421300)
‘Shu Guang’ Project supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation (No. 19SG26)
the Innovation Program of Shanghai Municipal Education Commission (No. 2017–01–07–00–02-E00010)
the Fundamental Research Funds for the Central Universities.