摘要
For glass-ceramics, how to realize the collaborative optimization of BDS and permittivity is the key toimprove the energy storage density. In this work, ZrO2 is introduced into BPKNAS glass-ceramics asnucleating agent to promote crystal development of glass-ceramics and then achieve high permittivity.When 1.5 mol% ZrO2 is added, the glass-ceramics have the highest permittivity (~128.59) and meanwhilepossess high BDS (1948.90 kV/cm) due to the dense microstructure. Therefore, BPKNAS-1.5ZrO2 glass-ceramics has the highest theoretical energy storage density (21.62 J/cm3). Moreover, the permittivityvariation of BPKNAS-1.5ZrO2 glass-ceramics is less than 6 % in the wide temperature range from 80 to300 C, showing excellent temperature stability. In addition, BPKNAS-1.5ZrO2 glass-ceramics possessesultrahigh power density, which reaches up to 382.40 MW/cm3 in overdamped circuit. The above evi-dence shows that BPKNAS-1.5ZrO2 glass-ceramics with ultrahigh energy storage density and powerdensity is very competitive in the field of energy storage applications.
基金
The authors acknowledge the Ministry of Science and Technol-ogy of China for its support through Project 973(Grant No.2015CB654601).
