摘要
Perovskite functional ceramics have been widely applied for thermal protection owing to their unique physical properties.However,formation of oxygen vacancies under external stimuli usually limits their performance in practical applications.Therefore,the mechanism of the effect of oxygen vacancy on the layer structure of perovskite La_(0.9)Sr_(0.1)TiO_(3+δ)was investigated by experiments and first-principles simulations.The experimental results showed that the lattice distortion occurred in oxygen-deficient environment to give a longer c-axis,along with a significant adjustment in the modes of A/B–O bond vibration,resulting in lower reflectivity.Advanced transmission electron microscopy studies revealed that oxygen vacancies induced localized atomic rearrangements via[TiO_(6)]layer movements to adapt to the lattice distortion.This eventually restructured a part of the layer interfaces by expanding the overlapping projection of atoms in the c-axial direction.The specific transformation process was described as a compendious process,while geometric phase analysis effectively clarified how oxygen vacancies can inhibit reflectivity on the layer structure.Thus,this study provides effective approaches for researching the effects of oxygen vacancy on the physical properties of orthorhombic layer perovskite structures,which may facilitate the development of perovskite-based functional devices.
基金
support received from National Natural Science Foundation of China(Grant No.52002355)
National Key Laboratory Foundation of Science and Technology on Materials under Shock and Impact(Grant No.6142902200202)
China Postdoctoral Science Foundation(Grant No.2019M652569)
Key Scientific Research Project of Colleges and Universities in Henan Province(Grant No.20A430025)
Henan Province Association for Science and Technology Young Talents Lifting Project(Grant No.2020HYTP021)。
