Ti-6Al-4V表面激光熔覆Ti/Stellite6复合涂层的组织与性能

Microstructure and Properties of Laser Cladded Ti/Stellite6 Composite Alloy Coating on Ti-6Al-4V Substrate

为提高钛合金的耐磨性能,本课题组设计了一种Stellite6和Ti粉的复合合金粉末20%Stellite6+80%Ti,并通过预热和保温处理,在Ti-6Al-4V(TC4)基材上激光熔覆了与基材结合良好的熔覆层,然后对熔覆层的物相、显微组织、元素分布、晶粒尺寸、硬度和耐磨性进行了研究。结果表明:熔覆层中的主要物相为β-Ti和CrTi固溶体,晶粒细小;在保温冷却过程中发生了相分离(β→β′+β);Co、Cr、W等原子的固溶强化、细小晶粒的细晶强化、第二相β′的弥散强化,使得熔覆层的硬度比基材提高了80 HV左右,磨损量减少了38%。

Objective The development of high-speed train has necessitated the use of lightweight materials.Titanium alloy has the characteristic of high specific strength,which makes it a promising material for reducing the weight of brake discs,but its wear resistance is low.Previous researchers studied wear-resistant coatings by the composite cladding of pure Co and Ti,relying on intermetallic compounds produced by high Co content to improve hardness;however,intermetallic compounds are not conducive for improving the comprehensive properties of coatings.Therefore,this study adopted the better performing Stellite6 alloy,which is a Co-based alloy,and designed a Ti-Co composite alloy with low Co content to improve the hardness and wear resistance of the coating while avoiding the formation of intermetallic compounds.Methods In this study,Ti-6Al-4V was used as a substrate,and Ti-Co alloy powder(20%Stellite6+80%Ti)was used as a cladding material to form the coating.Before cladding,the substrate was cleaned and preheated to 150℃.Simultaneously,the alloy powder was evenly mixed then dried at 100℃for 1h.For cladding,the optimal process parameters(such as laser power and scanning velocity)were used,along with high-purity argon as gas protection.After the cladding was completed,the sample was heat preserved with the substrate for 1hand then cooled down to room temperature with the substrate.Through X-ray diffraction(XRD),optical microscopy(OM),energy disperse spectroscopy(EDS),scanning electron microscopy(SEM),electron back-scattered diffraction(EBSD),and the Vickers hardness test,the phases,distributions of elements,microstructure morphologies,and hardness were analyzed.The interfacial bonding strength was also measured.Finally,the weight loss was calculated after friction and wear experiments.Results and Discussions The cladding layer has a microstructure characterized by black particles with a size less than5μm dispersed in the matrix(Fig.2).According to the elemental analysis,there are regions in the matrix that are rich in Co but deficient in Cr,and the C element in the dispersed black phase is relatively higher than that in the matrix(Fig.3).The EBSD phase identification shows that the cladding layer is mainlyβ-Ti solid solution(Fig.5)and CrTi4(Fig.4),and no intermetallic compounds are formed.Rich Co and less Cr areas are present during the formation of a solid solution.During the heat preservation and cooling process,theβ-Ti separation reaction takes place,which implies that theβ′phase,which is the dispersed particles with high carbon content,precipitates.The grain size analysis revealed that 80%of the grains are smaller than 30μm in diameter,belonging to the fine grain range(Fig.6).By observing the microstructure of the interface and micro-shear test,it can be seen that the interface is well combined(Fig.7and Fig.8).The interface’s minimum shear strength is 615 MPa,which is significantly higher than the substrate’s shear strength(509 MPa).The average hardness of the cladding layer is 372HV,which is approximately80HV higher than the substrate’s(Fig.9).The weight loss of the cladding layer is reduced by 38%compared with the substrate(Fig.10),which implies that the wear resistance is better than that of the substrate.It can be concluded that the abrasive wear occurs according to the grooves of the wear surface(Fig.11).Results show that the increase in the hardness and wear resistance is mainly due to the solid solution strengthening of generalizedβ-Ti solid solution,fine grain strengthening,and the diffusion strengthening of the second phaseβ′.Conclusions The composite Ti-Co alloy cladding layer(20%Stellite6+80%Ti)is well combined with the Ti-6Al-4Vsubstrate(the micro-shear strength is up to 615 MPa).Because of the low Co content and abundantβstable elements,the main phases of the cladding layer are solid solutionβ-Ti and CrTi4 without intermetallic compounds.80%of the grains are smaller than 30μm in diameter.During the heat preservation and cooling processes,theβ-Ti separation reaction takes place,which implies that theβ′phase precipitates as the black dispersed particles.The hardness of the cladding layer is increased by approximately 80HV,and the wear loss is reduced by 38%.The increase in the hardness and wear resistance is mainly due to the solid solution strengthening ofβ-Ti solid solution,fine grain strengthening,and the diffusion strengthening of the second phaseβ′.