摘要
借助化学改性手段制备了多种氨基酸功能基高分子吸附剂(LPPD),并考察了其从盐湖卤水中吸附铀的性能。结果表明:所制备的LPPD对从盐湖水中吸附铀有较好性能,吸附量达2.06 mg/g,吸附剂中赖氨酸功能基团与铀酰离子可形成3种稳定配位结构,并以化学控制为主的单分子层吸附机制吸附铀。
Multiple macromolecules with amino acid group were synthesized by chemical modifications,and its adsorption properties for uranium in salt lake brines were examined.The results show that the macromolecules with amino acid group can be used to adsorb uranium in salt lake brines,and the adsorption capacity for uranium can reach 2.06 mg/g.The amino acid group in the adsorbent can forming 3 types of coordination structures with uranyl ion.The adsorption mechanisms are single layer adsorptions and controlled by chemical reaction mainly.
作者
任宇
陈树森
勾阳飞
宿延涛
苏学斌
陈梅芳
曾广军
REN Yu;CHEN Shusen;GOU Yangfei;XU Yantao;SU Xuebin;CHEN Meifang;ZENG Guangjun(China National Uranium Co.,Ltd.,Beijing 100013,China;Beijing Research Institute of Chemical Engineering and Metallurgy,CNNC,Beijing 101149,China;Xi’an Lantian Uranium Co.,Ltd.,CNNC,Xi’an 710500,China)
出处
《湿法冶金》
CAS
北大核心
2022年第4期317-323,共7页
Hydrometallurgy of China
关键词
氨基酸
功能高分子材料
盐湖水
吸附
铀
amino acid
functional macromolecules
salt lake brine
adsorption
uranium