摘要
With the excessive consumption of nonrenewable resources,the exploration of effective and durable materials is highly sought after in the field of sustainable energy conversion and storage system.In this aspect,metalorganic frameworks(MOFs)are a new class of crystalline porous organicinorganic hybrid materials.MOFs have recently been gaining traction in energy-related fields.Owing to the coordination flexibility and multiple accessible oxidation states of vanadium ions or clusters,vanadium-MOFs(V-MOFs)possess unique structural characteristics and satisfactory electrochemical properties.Furthermore,V-MOFs-derived materials also exhibit superior electrical conductivity and stability when used as electrocatalysts and electrode materials.This review summarizes the research progress of V-MOFs(inclusive of pristine V-MOFs,V/M-MOFs,and POVbased MOFs)and their derivatives(vanadium oxides,carbon-coated vanadium oxide,vanadium phosphate,vanadate,and other vanadium doped nanomaterials)in electrochemical energy conversion(water splitting,oxygen reduction reaction)and energy storage(supercapacitor,rechargeable battery).Future possibilities and challenges for V-MOFs and their derivatives in terms of design and synthesis are discussed.Lastly,their applications in energy-related fields are also highlighted.
基金
National Research Foundation of Singapore(NRF)Investigatorship,Grant/Award Number:NRF2016NRFNRFI001‐22
National Natural Science Foundation of China,Grant/Award Numbers:51972067,22001021,51802044,51902062 and 5180204
Guangdong Natural Science Funds for Distinguished Young Scholar,Grant/Award Number:2019B151502039
Singapore MOE AcRF Tier 1,Grant/Award Number:2020‐T1‐001‐031
Natural Science Foundation of Jiangsu Province,Grant/Award Number:BK20201048
Natural Science Research Project of Higher Education Institutions in Jiangsu Province,Grant/Award Number:20KJB150008。