卟啉酞菁:从分子材料到聚集态

Porphyrin and phthalocyanine:from molecular materials to aggregates

卟啉酞菁类分子材料作为关键组分广泛应用于储能转换、光电子、催化、生物传感器等研究领域中.为了满足不同领域的实际需求,本课题组系统开展了分子结构设计、聚集态组装过程控制的相关研究,并对卟啉酞菁类材料的本征性质、聚集态形貌进行了系统的调控.本综述从卟啉酞菁类分子材料的分子结构修饰、聚集态调控和器件应用等方面出发,总结并讨论了相关领域的最新研究成果.此外,结合有机合成化学和自组装技术的设计策略,详细介绍了该类材料的设计原则、功能化结构修饰、自组装行为、器件应用和发展前景,为相关材料的设计与合成提供了重要的研究思路.

Molecular materials based on porphyrin and phthalocyanine are widely used as key components in the fields of energy storage conversion,photoelectronics,catalysis,and biomedicine.In order to meet the actual needs of different types of applications,molecular structure design and aggregation process control are being systematically carried out.The intrinsic properties and aggregation morphology of porphyrin and phthalocyanine molecules are systematically regulated.This review summarizes and discusses the research achievements of molecular materials based on porphyrin and phthalocyanine in the aspect of molecular structure modification,aggregation regulation,and device applications.The functionalization and development prospect of porphyrin and phthalocyanine-based materials are introduced in detail by combining the design strategy of organic synthetic chemistry and self-assembly technology.It provides important research ideas for the design and synthesis of related materials.