摘要
The crystal structure,martensitic transformation and magnetocaloric effect have been studied in all-d-metal Ni35Co15Mn33Fe2Ti15alloy ribbons with different wheel speeds(15 m/s(S15),30 m/s(S30),and 45 m/s(S45)).All three ribbons crystalize in B2-ordered structure at room temperature with crystal constants of 5.893(2)A,5.898(4)A,and5.898(6)A,respectively.With the increase of wheel speed,the martensitic transformation temperature decreases from230 K to 210 K,the Curie temperature increases slightly from 371 K to 378 K.At the same time,magnetic entropy change(△Sm)is also enhanced,as well as refrigeration capacity(RC).The maximum△Sm of 15.6(39.7)J/kg·K and RC of85.5(212.7)J/kg under?H=20(50)k Oe(1 Oe=79.5775 A·m^(-1))appear in S45.The results indicate that the ribbons could be the candidate for solid-state magnetic refrigeration materials.
作者
Yong Li
Liang Qin
Hongguo Zhang
Lingwei Li
李勇;覃亮;张红国;李领伟(Key Laboratory of Novel Materials for Sensor of Zhejiang Province,College of Materials&Environmental Engineering,Hangzhou Dianzi University,Hangzhou 310018,China;Faculty of Materials and Manufacturing,Key Laboratory of Advanced Functional Materials,Ministry of Education of China,Beijing University of Technology,Beijing 100124,China)
基金
Project supported by the National Natural Science Foundation of China(Grant Nos.52001102 and 51771003)。