Ti-6Al-4V梯度多孔结构的流通性与力学性能研究

Flowability and Mechanical Properties of Gradient Ti-6Al-4V Porous Structures

本文基于三周期极小曲面(TPMS)进行不同单元类型梯度孔隙率结构的优化设计,并进行静力学及粉末流体仿真,用于对比两种单元的应力集中程度和粉末流通能力。通过对比不同梯度孔隙率的两种单元发现,由于支柱设计类型不同,primitive单元相较于gyroid单元有着更优异的力学性能;5%梯度孔隙率(45%~50%)设计在两种单元中均有着最优的力学性能;相对于均匀孔隙率的gyroid单元多孔结构,5%梯度孔隙率primitive单元多孔结构的杨氏模量为7.34 GPa,仅提升了约3.93%,但其平均屈服强度可达到444.85 MPa,大幅提升约63.42%,平均抗压强度为606.57 MPa,提升了75.20%。本研究发现,屈服强度与有效支柱尺寸的相关性较强,抗压强度与应力集中程度的相关性较强。选择合适的多孔单元类型在与加载方向成45°夹角的位置进行孔隙率梯度调整,可使整体结构具有合适的孔径和支柱直径、优良的抗压能力、较小的应力集中程度以及较优异的粉末流通能力,最终可显著提升整体结构的力学性能。

Objective To prevent damage caused by stress-shielding effect,the Young’s modulus of a designed implant must be controlled at 3-30 GPa.Therefore,a porous structural design is necessary to adjust the Young’s modulus(110 GPa)of selective laser melted Ti-6 Al-4 V and to satisfy the mechanical properties of implants.The porous structure is necessary for appropriate Young’s modulus,extremely high strength and toughness,tissue growth,and biocompatibility.To obtain optimal mechanical properties,controlling the gradient porosity and gradient cell distribution is important.Gradient porosity was introduced in the model design.The stress concentration among the cells with different porosity gradients,powder flowability,and compressive mechanical properties were determined using the variant porosity gradients.Low-porosity units were used to optimize the porosity and mechanical properties,which were arranged in a high shear-strength zone located at45°-53°and perpendicular to the Y-Z plane.Methods The macroscopic morphology and particle-size distribution of powders were assessed using scanning electron microscopy and analyzed using ImageJ,as shown in Figs.1(a)and(b).The chemical compositions of the powders provided by the supplier are listed in Table 1.The substrate plate was made of Ti-6 Al-4 V to enhance the bonding strength.Two types of porous cells,i.e.,primitive(P)and gyroid(G)cells,with 40%,45%,and 50%porosity,were designed and built.The compressive samples was set to 6×6×6 cells according to according to the ISO 13314—2011 standard.The gradient porosity was distributed at a position perpendicular to the Y-Z plane and at 45°from the X-Y plane to improve the mechanical properties.The phase composition of the powders and printed samples were detected using X-ray diffraction.The stress concentration was calculated using the CAE-STANDARD solver.The optimal gradient porosities were determined based on the position of the stress concentration and strain.The powder-flowability analysis of each porous cell was simulated using Fluent.We assumed that the Ti-6 Al-4 V powder was in a discrete phase that would be bounced back from the wall,and air was solved using the STANDARD k-εturbulence model.Subsequently,the gas-solid mixed flow model was obtained.Results and Discussions P scaffolds with a 5%gradient porosity are best for subsequent model design and compressive testing.Simultaneously,G scaffolds with uniform porosity provide the best stress and strain distribution(Figs.8-10).Because of the strut distribution and extremely strong connectivity of the porous structure,the G cell exhibits a uniform airpressure distribution and stable powder-discharge speed when the porosity reaches 50%and 45%,respectively(Figs.11 and12).Each mechanical property of the P scaffolds is considerably superior than the G scaffolds(Fig.20).According to the simulation results(Figs.8-10),few stress concentrations occur in the P scaffolds,and the plastic-strain distribution caused by the deformation is uniform,which corresponds to better mechanical properties of the P scaffolds during the actual compression process because of the influence of the cell-strut type,degree of bending of the minimum strut size[Fig.14(b)],and effective strut size(Fig.8).We can observe that the yield strength is completely consistent with the minimum strut size[Figs.14(b)and 20(b)],indicating that the minimum strut size of the support shaft considerably affects the yield strength.Conclusions Static simulation of the porous structure with a 5%gradient porosity shows that a even stress distribution occurs in the P and G scaffolds,which can well satisfy the implant requirements of internal printing quality and mechanical properties.Simultaneously,the larger pore size of the P cell makes the powder-discharge capacity stronger.From the analysis of the mechanical properties of each gradient porous structure,we find that a larger effective strut size of the P scaffolds leads to a uniform stress distribution,which greatly promotes the mechanical properties.From the compression test of the P and G cells,because of the reasonable stress concentration and increased density of the cell at the 45°position,the45%-50%gradient porosity structure demonstrates a substantial improvement in the mechanical properties compared with the 50%uniform porosity structure.When the porosity gradient continues to increase,a serious stress concentration owing to unit dislocation causes the overall mechanical property to decrease.