Progress on Space Materials Science in China:Debris Shielding Fibrous Materials and High Specific Energy Lithium Sulfur Batteries

The development of China’s space industry puts forward urgent requirements for high-performance debris shielding materials and high energy density rechargeable battery.In this review,the recent progress on debris shielding fibrous materials and high energy density Li-S battery are particularly summarized.According to the experimental results,basalt fibers and silicon carbide fibers were chosen as the effective filling shielding materials.The geometric structure of fabrics was also investigated.For the novel shielding materials,high-strength and flexible silicon carbide micro-nano fibrous membranes were designed and fabricated.The obtained membranes with excellent mechanical properties portend the potential applications in debris protection structure.Furthermore,the high specific energy lithium sulfur batteries have made remarkable progress in fundamental research and application research in recent years.In order to solve the key problems of polysulfides shuttle and slow redox kinetics in lithium sulfur battery,a series of transition metal compound@hollow carbon-based material as sulfur host with dual functions of catalysis and adsorption towards polysulfides were designed and constructed.The obtained Li-S pouch cells with high areal sulfur loading of 6.9 mg·cm^(-2)yield exceptional high practical energy density of 382 W·h·kg^(-1)under lean electrolyte of 3.5μL·mg^(-1),demonstrating the great potential of realistic high-energy Li-S batteries.