摘要
发展了一种温和条件下以甲酸盐作为还原剂和羰基来源的β-选择性烯烃氢羧化反应.利用该方法,一系列的烯烃能够被有效地转化为高价值的羧酸产品.该方法具备催化剂用量小、官能团耐受性好、易于放大等特点.
A transition-metal-freeβ-selective hydrocarboxylation of alkenes under mild conditions has been developed using a formate salt as the reductant,carbonyl source.A broad range of alkenes were compatible with this method and can be efficiently converted into value-added carboxylic acid products.This method also features low catalyst loading,good functional group tolerance,and easy scalability.
作者
黄燕
张谦
詹乐武
侯静
李斌栋
Huang Yan;Zhang Qian;Zhan Lewu;Hou Jing;Li Bindong(College of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2022年第8期2568-2573,共6页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.21901118)
江苏省自然科学基金(No.BK20190430)
重点高校基础科研业务费专项资金(No.30921011206)资助项目.
关键词
烯烃
氢羧化
光催化
二氧化碳自由基负离子
甲酸盐
alkenes
hydrocarboxylation
photocatalysis
carbon dioxide radical anion
formate salt
