唐家会矿煤自燃热反应动力学研究

Study on thermal reaction kinetics of long flame coal spontaneous combustion in Tangjiahui Mine

为有效防治唐家会矿煤自燃灾害,利用热重实验,分析了煤样在不同升温速率和不同氧气体积分数下热反应动力学特征。结果表明:在相同氧气体积分数下,升温速率2、5、10℃/min煤的表观活化能分别为150.27、131.97、106.86 k J/mol;相同升温速率下,氧气体积分数为6%、9%、12%、15%、18%、21%煤的表观活化能分别为106.86、120.61、127.31、131.58、135.26、136.82kJ/mol,表观活化能随着升温速率和氧气体积分数的增大而减小,变化规律基本符合对数函数递增;活化能动力学计算结果揭示了不同升温速率和不同氧气体积分数下,燃烧阶段煤氧复合反应程度不同。

In order to effectively prevent and control coal spontaneous combustion disasters in Tangjiahui Mine, thermogravimetric experiments were used to analyze the thermal reaction kinetics characteristics of coal samples at different heating rates and different oxygen volume fractions. The results showed that at the same oxygen volume fraction, the apparent activation energies of coal at heating rates of 2 ℃/min, 5 ℃/min, 10 ℃/min were 150.27 kJ/mol, 131.97 kJ/mol, 106.86 kJ/mol, respectively;in addition, at the same heating rate, the apparent activation energies of coals with oxygen volume fraction of 6%, 9%, 12%, 15%,18%, 21% are 106.86, 120.61, 127.31, 131.58, 135.26 and 136.82 kJ/mol, respectively. The apparent activation energies decrease with the increase of heating rate and oxygen volume fraction, and the change law is basically in line with the increase of logarithmic function. The calculation results of activation energy kinetics reveal that the degree of coal-oxygen composite reaction is different under different heating rates and different oxygen volume fractions.