解析烯烃单体聚合热力学

Thermodynamics Analysis of Olefin Monomer Polymerization

高分子化学是继四大基础化学课程后开设的综合性较强的一门专业课程,在高分子化学理论课教学中,烯烃单体的聚合是重要知识点,其聚合产物也是使用最为普遍的聚合物材料。烯烃单体能否成功聚合需要从化学反应热力学和动力学两个方面来探讨,化学反应热力学的相关判据及热力学参数能够为聚合反应提供方向性和聚合极限的重要信息,本文主要探讨烯烃单体的聚合热力学问题。

Polymer Chemistry is a comprehensive professional course following the four basic chemistry courses, and in the theoretical teaching of Polymer Chemistry, the polymerization of olefin monomer is one of the important knowledge points, and its polymerisate is also the most commonly used polymer material. Whether olefin monomer could be polymerized needs to be discussed from two aspects of chemical reaction thermodynamics and kinetics. The relevant criteria and thermodynamic parameters of chemical reaction thermodynamics could provide important information of reaction direction and polymerization limit for polymerization reaction. This paper mainly discusses the polymerization thermodynamics of olefin monomer.