过渡金属催化的内烯烃不对称硼氢化

Transition Metal Catalyzed Asymmetric Hydroboration of Internal Alkenes

金属催化的烯烃不对称硼氢化是构建手性硼酸酯最为有效的方法之一,具有原料简单易得、原子经济性高、硼化产物结构多样等特点,受到化学家的广泛关注.总结了过渡金属催化的内烯烃的不对称硼氢化,包括张力环状内烯烃、苯乙烯类内烯烃及含配位基团的内烯烃.

Transition metal catalyzed asymmetric hydroboration of alkenes is one of the most powerful methods to prepare chiral organoboronates, which has attracted extensive attention of chemists due to its simple raw materials, high atomic economy, diverse structure of borated products, etc. The transition metal catalyzed enantioselective hydroboration of internal alkenes including strained internal alkene, β-substituted styrenes and internal alkenes bearing a coordinating group is summarized.