摘要
There is a great demand for self-assembled carbon nanomaterials because of their importance in optoelectronics,biomaterials,and so forth.Herein,we report a novel type of self-assembled,nanoscale,crystalline vesicle from nonplanarπ-conjugated nanocycles.We designed four different structural[8]cycloparaphenylenes([8]CPPs)molecules and demonstrated that these nonplanarπ-conjugated CPP nanocycles could self-assemble into multilamellar,crystalline vesicles in tetrahydrofuran(THF)/H2O mixed solvent.
基金
supported by the Natural Science Foundation of China(nos.51690153 and 21720102005)
the National Key R&D Program of China(nos.2017YFA0701301 and 2017YFA0205401)
the Program for Changjiang Scholars and Innovative Research Team in University.
