摘要
Room-temperature switchable materials showing multiple responses toward external stimuli are highly desired.Herein,we report bidirectional spin-state switch and fluorescence modulation of an Fe(II)complex(1)based on a rhodamine B 2-pyridinecarbaldehyde hydrazone ligand in both the solid state and solution.The complex is predominantly stabilized in the low-spin(LS)state at room temperature due to the strong ligand-field strength imposed by acylhydrazone pyridine.
基金
supported by the National Natural Science Foundation of China(nos.21871140 and 21401104).
