摘要
A novel photocatalyzed trifluoromethylthio-trifluoromethylation of alkenes has been developed,using CF_(3)SO_(2)Na as both CF_(3) and SCF_(3) source.This photocatalyzed dual-oxidative strategy,which combines two parallel oxidative events,provides a facile method to synthesize a series of vicinal trifluoromethylthio-trifluoromethylated compounds.This reaction is operationally simple,proceeds under mild conditions and exhibits exceptional substrate generality and functional group compatibility.
基金
This research was made possible as a result of a generous grant from XYZ Foundation(grant no.123567).
