摘要
The study of small-molecule activation by f-block elements still lags far behind that of transition metals.Although a few uranium complexes have been reported to activate dinitrogen,reports on the activation of heavier congeners,such as white phosphorus(P_(4)),by uranium species are extremely rare,and no example of uranium-mediated activation of elemental arsenic has appeared.
基金
supported by the National Natural Science Foundation of China(grant nos.21772088 and 91961116)
the Fundamental Research Funds for the Central Universities(nos.14380216 and 14380262)
Programs for high-level entrepreneurial and innovative talents introduction of Jiangsu Province(individual and group programs).L.M.is a senior member of the Institut Universitaire de France.The Humboldt Foundation and Chinese Academy of Science are acknowledged for financial support。
