摘要
近年来,由于自由基反应在碳-碳键构筑中独特的作用,有机化学家相继开发了各种自由基前体化合物。N-取代丁二酰亚胺(NHPI)还原活性酯作为一种重要的自由基前体化合物,近期受到了有机化学家的广泛关注。本文综述了该领域的最新研究进展,主要介绍在电、金属催化条件下,自由基诱导N-取代丁二酰亚胺酯类化合物参与的碳-碳键构筑。
Recently,organic chemists continuously developed a great variety of radical precursors with the unique role of free radical reactions in the construction of carbon-carbon bonds.Especially,(N-acyloxy)phthalimide(NHPI)esters,a class of radical precursors compounds with great significance,has been widely concerned by scientists.In this perspective article,we will systematically summarize the advance in the field of the radical-induced of(N-acyloxy)phth-alimide esters to construct carbon-carbon bond according to the catalyst type,including electrochemical catalysis and metal catalysis.Meanwhile,pathways for future development have been proposed.
作者
梁炳玉
路博华
陶乐
李玉江
王清龙
董黎红
郭晓河
田云飞
LIANG Bingyu;LU Bohua;TAO Le;LI Yujiang;WANG Qinglong;DONG Lihong;GUO Xiaohe;TIAN Yunfei(High&New Technology Research Center of Henan Academy of Science,Zhengzhou 450002,Henan,China;Department of Science,Henan University of Animal Husbandry and Economy,Zhengzhou 450011,Henan,China;College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang 471000,Henan,China)
出处
《化学研究》
CAS
2023年第1期85-94,共10页
Chemical Research
基金
河南省自然科学基金(202300410290)
河南省科学院基本科研费项目(220602011)。
关键词
金属/电催化
N-取代丁二酰亚胺酯
碳-碳键
自由基化学
metal/electric catalyst
(N-acyloxy)phthalimide esters
carbon-carbon bonds
free radical chemistry