钛合金表面自润滑复合耐磨结构的制备及其摩擦性能研究

Preparation and Tribological Properties of Self-Lubricating Composite Wear-Resistant Structure on Titanium Alloy Surface

本文中采用激光微加工法在TC4钛合金表面制备了不同形貌与分布密度的微观织构,将表面织构、热氧化膜与PTFE润滑薄膜相复合制备了自润滑复合耐磨结构,同时考察了滑动条件下织构形貌及织构密度对这一复合结构摩擦磨损性能的影响.结果表明:与未织构面的润滑薄膜相比,织构面薄膜的结合力明显增大,表面织构与润滑薄膜的结合显著增强了材料的减摩抗磨性能.在最优的织构密度下,含有薄膜的织构化钛合金表面的磨损率可降低至1.5×10^(-6)mm^(3)/(N·m),较未织构面润滑薄膜的磨损率降低了99.3%.而将经热氧化的织构表面与润滑薄膜的结合则进一步提升了材料的耐磨性,热氧化织构面润滑薄膜的磨损率最低可达8.0×10^(-7)mm^(3)/(N·m),与未热氧化的织构面润滑薄膜相比,磨损率降低了46.1%.在相同的织构间距条件下,线型热氧化织构面显示出低而稳定的摩擦系数与极低的磨损量,这主要得益于高密度微织构对润滑介质的有效补充以及高硬度热氧化膜的耐磨性起到了协同减摩抗磨的作用.

With the development of aerospace equipment,titanium alloy is more and more used in aerospace equipment components because of its many advantages.At the same time,the poor tribological properties of titanium alloy limit its further application in the field of tribology.In this study,the micro-structures with different morphologies and texture densities were prepared on the surface of TC4 titanium alloy by laser micromachining.The self-lubricating composite wear-resisting structures were prepared by combining surface texture,thermal oxidation film and PTFE lubrication film on the TC4 surface.The effects of texture morphology and texture density on the friction and wear properties of the composite structure under sliding condition were investigated,and the friction-reducing and anti-wear mechanism between PTFE lubrication film and micro-texture of titanium alloy surface was analyzed.The impact of introducing of thermal oxidation film on wear life was further studied.The results showed that the lubricating film on the untextured surface of the titanium alloy had a high and fluctuating friction coefficient,showing severe wear.However,the adhesion force of film on the textured surface increased significantly.Compared with the lubricating film of untextured surface,the combination of textured surface and lubricating film can significantly enhance the friction reduction and wear resistance of the material.With the increase of texture density,the friction coefficient and wear rate were further reduced.Under the optimal texture density,the lowest friction coefficient reached 0.11,and the wear rate of the textured titanium alloy with the film was 1.5×10^(-6) mm^(3)/(N·m),which was 99.3% lower than the wear rate of the untextured lubricating film.On the other hand,the combination of thermal oxidized textured surface and lubricating film further improved the wear resistance of material surface.The friction coefficient of the composite structure was as low as 0.12,and the wear rate of the lubricating film with thermal oxidized textured surface was as low as 0.8×10^(-6) mm^(3)/(N·m),which was 46.1%lower than the wear rate of the lubricating film on non-oxidized textured surface.The linear thermal oxidized textured surfaces exhibited low and stable friction coefficient and extremely low wear rate at the same texture spacing comparing the circular thermal oxidized textured surfaces.It can be considered that the effective supplement of high density texture to lubricating medium and the wear resistance of high hardness thermal oxidation film played a synergistic role in reducing friction and anti-wear.