金属酞菁的二维有机框架材料的合成及其应用

Synthesis and application of two-dimensional organic framework materials based on metal phthalocyanine

金属酞菁(MPcs)二维(2D)有机框架在吸附与分离、催化、生物化学等方面具有广泛的应用价值.基于MPcs的2D框架的合成和研究,为发展新兴的具有电、磁、光和电化学特性的多功能材料提供了新的途径.文章首先介绍了构筑2D有机框架的MPcs分子单体的结构功能关系,以及2D有机框架材料的历史发展和独特功能;其次介绍了由MPcs构建的二维金属有机框架材料(MPcs-2D MOFs)和MPcs二维共价有机框架材料(MPcs-2D COFs)的合成方法;最后总结了两者在传感器、催化、能量储存和光动力治疗方面的应用.

The two-dimensional(2D) organic frames of metal phthalocyanines(MPcs) have wide application value in adsorption and separation, catalysis, biochemistry and so on. The synthesis and research of 2D frames based on MPcs provide a new way to develop new multifunctional materials with electrical, magnetic, optical, and electrochemical properties. In this paper, firstly, the structurefunction relationship of metal phthalocyanine monomers for constructing 2D organic framework and the historical development and unique functions of 2D organic framework materials are introduced. Secondly, the synthesis methods of metal-phthalocyanines 2D metalorganic framework materials(MPcs-2D MOFs) and metal-phthalocyanines 2D covalent organic framework materials(MPcs-2D COFs) were introduced. Finally, their applications in sensor, catalysis, energy storage, and photodynamic therapy are summarized.