摘要
We report the layering and liquid–liquid phase transition of liquid titanium confined between two parallel panel walls.Abnormal changes in the volume and the potential energy confirm the existence of the liquid–liquid phase transition of the liquid titanium. The typical feature of the liquid–liquid phase transition is layering, which is induced by the slit size,pressure and temperature. We highlight the fact that the slit size and pressure will determine the number of layers. In addition, with the change in the slit size, the density of the confined liquid expresses a fluctuating law. The phase diagram of the layering transition is drawn to clearly understand the layering. This study provides insights into the liquid–liquid phase transition of liquid metal in a confined space.
作者
张迪
段云瑞
郑培儒
马英杰
钱俊平
李志超
黄建
蒋妍彦
李辉
Di Zhang;Yunrui Duan;Peiru Zheng;Yingjie Ma;Junping Qian;Zhichao Li;Jian Huang;Yanyan Jiang;Hui Li(Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials,Ministy of Education,Shandong University,Jinan 250061,China;Cllege of Materials SCience and Engineering,Taiyuan University of Technology,Taiyuan 030024,China)
基金
supported by the National Natural Science Foundation of China (Grant Nos. U1806219 and 52171038)
the Special Funding in the Project of the Taishan Scholar Construction Engineering and the Program of Jinan Science and Technology Bureau (Grant No. 2020GXRC019)
Key R&D Projects in Shandong Province, China (Grant No. 2021SFGC1001)。
