摘要
利用4-氨基甲基吡啶与马来酸酐接枝线型低密度聚乙烯(LLDPE-g-MAH)成功制备了氨基甲基吡啶接枝线型低密度聚乙烯(LLDPE-g-Py),然后采用熔融共混法制备了改性的BN/LLDPE(mBN/LLDPE)复合材料。深入研究了mBN/LLDPE复合材料的热性能和力学性能等。结果表明,LLDPE-g-Py的加入,使mBN/LLDPE复合材料的导热性能得到很大提升,但LLDPE-g-Py过多会导致其耐热性降低。为了改善复合材料的耐热性,将LLDPE-g-Py质量分数固定为10%。当BN质量分数为40%时,mBN/LLDPE复合材料的导热系数达到了0.95 W/(m·K),为纯LLDPE导热系数(0.32 W/(m·K))的3倍。同时,mBN/LLDPE复合材料的拉伸强度在小幅度下降的情况下,其断裂伸长率得到明显的改善。
Aminomethylpyridine grafted linear low density polyethylene(LLDPE-g-Py)was successfully prepared with 4-aminomethylpyridine and maleic anhydride grafted linear low density polyethylene(LLDPE-g-MAH),and then the modified BN/LLDPE(mBN/LLDPE)composites were prepared by melt blending.In the composites,due to the non-covalent action of LLDPE-g-Py and BN,the interfacial thermal resistance between filler and matrix is reduced,and BN is evenly dispersed in LLDPE matrix,so as to enhance the thermal conductivity of the composite.The thermal and mechanical properties of mBN/LLDPE composites were deeply studied.The results show that the thermal conductivity of mBN/LLDPE composites is greatly improved by the addition of LLDPE-g-Py,but too much LLDPE-g-Py will reduce its heat resistance.In order to improve the heat resistance of the composite,the LLDPE-g-Py mass fraction is fixed at 10%.When the BN mass fraction is 40%,the thermal conductivity of mBN/LLDPE composite reaches 0.95 W/(m·K),which is about 3 times that of pure LLDPE(0.32 W/(m·K)).At the same time,the tensile strength of mBN/LLDPE composites decreases slightly,and its elongation at break is significantly improved.
作者
唐敢
柯雪
董姗
张兆阳
游峰
陈蓉
刘仿军
江学良
Gan Tang;Xue Ke;Shan Dong;Zhaoyang Zhang;Feng You;Rong Chen;Fangjun Liu;Xueliang Jiang(Hubei Key Laboratory of Plasma Chemistry and New Materials,School of Materials Science&Engineering,Wuhan Institute of Technology,Wuhan 430205,China;Ministry of Education Key Laboratory for Green Preparation and Application of Functional Materials,School of Materials Science and Engineering,Hubei University,Wuhan 430062,China;Polymer Research Institute of Sichuan University,Chengdu 610065,China)
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
2023年第2期43-50,共8页
Polymer Materials Science & Engineering
基金
功能材料绿色制备与应用教育部重点实验室(湖北大学)开放基金(202105)
广东省基础与基础应用研究基金(2019A1515110465)。
关键词
复合材料
线型低密度聚乙烯
氮化硼
导热性
力学性能
composites
linear low density polyethylene
boron nitride
thermal conductivity
mechanical properties