摘要
The freshness of seafood can be judged by detecting the concentration of triethylamine(TEA). In this work, 2D Cu O porous nanosheets(Cu O PNs) were prepared by a graphene oxide template method and their particle sizes were regulated by changing the calcination temperature. Their structure, morphology and gas sensing performances were investigated by various characterization methods. The response(Rg/Ra) of the gas sensor based on Cu O PNs calcined at 700oC was as high as 440-100 ppm TEA at the operating temperature of 40 ℃. The detection limit was as low as 0.25 ppm. In addition, the gas sensor has good selectivity and stability. The excellent TEA sensitivity is mainly resulted from the appropriate particle size and loose porous framework. This work not only paves the way to explore the novel low temperature TEA gas sensors, but also provides deep insight on improving the structure and properties of gas sensitive materials by controlling the calcination temperature.
基金
financially supported by the National Natural Science Foundation of China (No. 62071300)
Science and Technology Commission of Shanghai Municipality (Nos. YDZX20213100003002, 19ZR1435200, 20490761100)
Innovation Program of Shanghai Municipal Education Commission (No. 201901-07-00-07-E00015)
Program of Shanghai Academic/Technology Research Leader (No. 19XD1422900)
Key Basic Research Program of Science and Technology Commission of Shanghai Municipality (No. 20JC1415300)
Foshan Science and Technology Innovation Program (No. 2017IT 100121)。