摘要
Acetylene purification from methane is challenging in the field of porous organic polymers(POPs).Herein,we have provided one-pot Ullmann coupling reaction to synthesize a series of POPs with rich N-sites,named FJU-POP-n,wherein the low-cost and non-toxic Cu(acac)2 and environmental-friendly glycerol are employed as catalyst and solvent,respectively.
基金
This work was financially supported by the National Natural Science Foundation of China(grant nos.21975044,21971038 and 219722810)
Fujian Provincial Department of Science and Technology(2018J07001,2019L3004,2019H6012 and 2021H0062).
