TiO_(2)纤维在光催化还原CO_(2)中的应用

Application of photocatalytic titanium dioxide fibers in carbon dioxide reduction

以二氧化碳(CO_(2))为代表的温室气体可以利用催化剂在太阳光的作用下转化为可回收产物。TiO_(2)化学性能稳定、毒性低且生物友好,是制备高效光催化剂的备选原料之一。本文对TiO_(2)催化机理、主要成形工艺和相关改性处理方法进行介绍,并分析材料内部电子运动、光生电子空穴分离和光子吸收效率,探究其对以TiO_(2)为主体的纳米纤维光催化效率的影响。通过分析对比,为TiO_(2)纤维结构的设计和对应CO_(2)产物的还原研究提供思路。

Titanium dioxide(TiO_(2))is an important inorganic material with stable chemical properties,low toxicity and biocompatibility.In particular,its photochemical properties have played a good catalytic effect in hydrogen evolution,wastewater degradation and waste gas treatment.In recent years,with the increase of carbon emissions,the application of TiO_(2)-based photocatalytic materials in CO_(2) reduction has been widely studied.Compared with nanoparticles,TiO_(2) materials with nanofiber structure stand out due to their efficient photogenerated electron-hole separation behavior and excellent catalytic stability.Therefore,the exploration of the forming process and material compounding of TiO_(2) is constantly advancing its carbon reduction efficiency to the expected industrial application.TiO_(2) can be designed as a nanofiber structure,which extends the reaction path of photogenerated electrons by virtue of its closely connected interworking structure,so as to improve the rapid recombination of electron holes in nanoparticles.Hydrothermal method is a common method to prepare nanofibers from inorganic metals,and TiO_(2) nanofibers with different crystal forms and special structures can be produced by adjusting the heating time and temperature during the reaction.Electric field can stretch the spinning solution fluid in the electrospinning method.TiO_(2) nanofibers can be prepared with larger length with the help of easily removed polymer spinning carrier.Likewise,different catalytic aids can be doped in the TiO_(2) structure.Nanofibers with smaller diameter can be grown on mesoporous carriers by vapor phase growth method,and the catalyst is uniformly dispersed.In addition,supercritical synthesis,anodic oxidation and laser ablation can be used to prepare TiO_(2) nanofibers.The wide band gap of TiO_(2) makes it have a short absorption wavelength,which makes it difficult to use sunlight efficiently.In order to further improve the photocatalytic performance,compounding or doping on TiO_(2) nanofibers(heterojunction)can reduce the band gap width and improve the photon absorption rate while ensuring the catalytic efficiency.Common metal doping materials include gold,platinum,copper,etc.,and the doping of non-metallic elements such as carbon,nitrogen and sulfur also helps to increase the light absorption wavelength of TiO_(2).In summary,the photocatalytic effect of TiO_(2) with nanofiber structure in CO_(2) reduction has been widely studied.The analysis of its catalytic mechanism often focuses on the transformation of TiO_(2) crystal form,the rate of photogenerated electron movement and the movement effect of various particles.However,the application of TiO_(2) nanofibers in carbon reduction is still in the laboratory stage.How to comprehensively design a structure to use in the industrialized waste gas treatment process is still one of the problems that researchers need to solve.At present,the widely used electrospinning technology can design multiple elements into the microstructure of TiO_(2)-based photocatalytic materials.Combined with the flexibility and integration of nanofibers,the catalytic efficiency of CO_(2) reduction can be further improved from both material and structure.