摘要
金属有机多面体(MOPs)是由无机金属离子和具有特定结构的有机配体通过自组装的形式合成的。MOPs是一种高度有序和离散分子结构的无机有机杂化材料,具有高孔隙率、可调节的孔径、化学稳定性以及可定制的功能等特点,应用前景广阔。总结了MOPs的制备方法及应用进展,指出了MOPs材料发展的制约因素及未来MOPs材料的发展方向。
Metal-organic polyhedra(MOPs)are synthesized by self-assembly of inorganic metal ions and organic ligands with specific structures.MOPs are inorganic-organic hybrid materials with highly ordered and discrete molecular structures.They are characterized by high porosity,adjustable pore size,chemical stability,and customizable functions,and have promising applications.In this paper,we summarized the preparation methods and applications of MOPs,pointed out the constraints on the development of MOPs materials,and proposed the future development direction of MOPs materials.
作者
段欣博
杨志远
鞠晓茜
王昌国
Duan Xinbo;Yang Zhiyuan;Ju Xiaoqian;Wang Changguo(College of Chemistry and Chemical Engineering,Xi'an University of Science and Technology,Xi'an 710054;Key Laboratory of Coal Resources Exploration and Comprehensive Utilization of Land and Resources,Xi'an 710021)
出处
《化工新型材料》
CAS
CSCD
北大核心
2023年第4期20-25,共6页
New Chemical Materials
基金
国家自然科学基金(41772166)
陕西省重点研发计划(2017ZDCXL-GY-10-01-02,2018GY-076)
自然资源部煤炭资源勘查与综合利用重点实验室重大专项(SMDZ-2019ZD-2)
重点实验室自主课题(ZP2019-1)。
关键词
金属有机多面体
合成方法
分类
应用前景
metal-organic polyhedra(MOPs)
synthesis method
classification
application prospect