期刊文献+

在CuAAC反应中具有高活性、无氧化剂和高稳定性的Cu@GO催化剂的制备

Preparation of Cu@GO with Highly Active,Oxidant-free and High Stable in CuAAC Reaction
下载PDF
导出
摘要 我们报道了一种具有良好的催化性能和稳定性的非均相催化剂Cu@GO。研究了该催化剂在水相CuAAC反应中的性能。结果表明,在不添加氧化剂的情况下,Cu@GO催化剂具有与CuI等均相亚铜催化剂相似的催化活性。此外,该催化剂在CuAAC反应中至少可以循环使用10次,且具有较高的产率。 The use of Cu@GO was reported as a heterogeneous catalyst with good catalytic performance and stability.The performance of this catalyst in the aqueous phase CuAAC reaction was investigated,and the results showed that the Cu@GO catalyst had an excellent catalytic activity similar to that of homogeneous cuprous catalysts such as CuI without the addition of oxidant.In addition,the prepared catalyst could be recycled at least 10 times in the CuAAC reaction and has a high yield.
作者 郭秀民 吴一帆 王慧慧 姚莹 吴立峰 沈永杰 朱丹诚 GUO Xiu-min;WU Yi-fan;WANG Hui-hui;YAO Ying;WU Li-feng;SHEN Yong-jie;ZHU Dan-cheng(College of Biology and Environmental Engineering,Zhejiang Shuren University,Zhejiang Hangzhou 310015;Ningbo Dachang Pharmaceutical Company Limited,Zhejiang Ningbo 315502,China)
出处 《广州化工》 CAS 2023年第5期51-54,共4页 GuangZhou Chemical Industry
基金 浙江省自然科学基金项目(No:LQ21E020003) 2021年全国大学生创新创业训练计划项目(项目编号:202111842010)。
关键词 CuAAC反应 氧化石墨烯 非均相催化 CuAAC reaction graphene oxide heterogeneous catalysis
  • 相关文献

参考文献2

二级参考文献60

  • 1Tomφe C W, Christensen C, Meldal M. Peptidotriazoles on solid phase: [ 1,2,3 ] -triazoles by regiospecific copper (I) -catalyzed 1,3 -dipolar cycloadditions of terminal al- kynes to azides [ J ]. J. Org. Chem. , 2002, 67 (9) : 3 057 - 3 062.
  • 2Rostovtsev V V, Green L G, Fokin V V, Sharpless K B. A stepwise Huisgen cycloaddition process: copper ( Ⅰ ) - catalyzed regioselective "ligation" of azides and terminal alkynes[J]. Angew. Chem. Int. Ed., 2002, 41(14): 2 596 - 2 599.
  • 3Tucker S H. Iodination in the carbazole series [ J ]. J. Chem. Soc., 1926, 546 -553.
  • 4Fumio S, Ritsuya K, Masashi S. , et al. Synthesis and properties of polyacetylenes connecting carbazole at the 2 - and 3 - positions: effect of polymerization catalysts and substitution positions on the optoelectronic properties [ J ]. Macromol. Chem. Phys. , 2007, 208(2): 765 -771.
  • 5Qu J Q, Jiang F, Chen H Q. , et al. Synthesis and pho- toisomerization of poly( 1 - methylpropargyl ester) s carry- ing azobenzene moieties [ J ]. J. Polym. Sci. , Part A : Polym. Chem. , 2009, 47(18) : 4 749 -4 761.
  • 6Priimagi A, Vapaavuori J, Rodriguez F J. , et al. Hydro- gen - bonded polymer - azobenzene complexes : enhanced photoinduced birefringence with high temporal stability through interplay of intermolecular interactions [ J ]. Chem. Mater. , 2008, 20(20) : 6 358 -6 363.
  • 7Jiang F, Qu J Q, Chen H Q. Synthesis and characteriza- tion of poly( chiral methylpropargyl ester)s carrying azo- benzene moieties [ J ]. Chinese J. Chem. , 2009, 27 (10) : 2 079 -2 084.
  • 8Qin A, Jim C K W, Lu W, Lain J W Y, Halussler M, Dong Y, Sung H H Y, Williams I D, Wong G K L, Tang B Z. Click polymerization: facile synthesis of functional poly (aroyltriazole) s by metal - Free, regioselective 1,3 - dipolar polycycloaddition [ J ]. Macromolecules, 2007, 40(7) : 2 308 -2 317.
  • 9Chattopadhyay D. K., Webster D. C., Prog. Polym. Sci., 2009, 34(10), 1068—1133.
  • 10Lee S. K., Kim B. K., J. Colloid Interface Sc., 2009, 336(1), 208—214.

共引文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部