摘要
In this work,a series of Pr^(3+)ions doped(Sr,Ba)LaMgTaO_(6)phosphors were prepared and applied for plant growth lighting.Under 450 nm excitation,(Sr,Ba)LaMgTaO_(6):Pr^(3+)exhibits intense reddish emission at around 650 nm which is assigned to the3p0→3F2transition of Pr^(3+)ions.The luminescence intensity reaches to the maximum at 2.5 mol%Pr^(3+)doping content both in SrLaMgTaO_(6):Pr^(3+)and BaLaMgTaO_(6):Pr^(3+)systems.Meanwhile,the internal quantum efficiency(IQE)test shows that the IQE of the SrLaMgTaO_(6):0.025Pr^(3+)phosphor is 33.34%upon blue light excitation.The decay curves and temperature-dependent luminescence measurements of the(Sr,Ba)LaMgTaO_(6):Pr^(3+)phosphors were performed and investigated in detail.The red light emitting diodes(LEDs)were packaged using the SrLaMgTaO_(6):Pr^(3+)and BaLaMgTaO_(6):Pr^(3+)phosphors combined with a blue LED chip,which are welloverlapped with the absorption band of photosynthesis.Results indicate that the(Sr,Ba)LaMgTaO_(6):Pr^(3+)can serve as a component of the red light in plant-growth LEDs.
基金
supported by the National Natural Science Foundation of China(51772287,61804028)。