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CO_(2)加氢制高碳α-烯烃Fe基催化剂研究进展 被引量:2

Research progress on Fe-based catalysts for CO_(2) hydrogenation to high carbonα-olefins
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摘要 随着“双碳”目标的提出,二氧化碳(CO_(2))减排和资源化利用受到研究者的广泛关注。CO_(2)耦合绿氢技术制高附加值化学品是CO_(2)资源化利用的有效途径之一。高碳α-烯烃是重要的化工原料,围绕非均相催化体系催化CO_(2)加氢制高碳α-烯烃的相关研究,总结分析了CO_(2)加氢制高碳α-烯烃的催化剂设计理念、反应机理、助剂、载体以及制备工艺对催化剂催化性能的影响和构效关系。其中,设计高效催化剂有效调控C—O键活化和C—C链增长仍存在挑战。对CO_(2)加氢制高碳α-烯烃的发展方向进行了展望,可为CO_(2)加氢制高碳α-烯烃新型催化剂的开发提供参考。 With the proposal of“carbon peaking and carbon neutrality”goals,carbon dioxide(CO_(2))emission reduction and resource utilization have attracted extensive attention from researchers.The production of high value-added chemicals by CO_(2) coupled with green hydrogen technology is one of the effective ways of CO_(2) resource utilization.The high carbonα-olefin is an important chemical raw material.Based on the research on the production of high-carbonα-olefin from CO_(2) hydrogenation by heterogeneous catalytic system,the influence of catalyst design concept,reaction mechanism,promoter,support and preparation process on the catalytic performance and the structure-activity relationship were summarized and analyzed.Among them,there are still challenges in designing efficient catalysts to effectively regulate C—O bond activation and C—C chain growth.The development direction of CO_(2) hydrogenation to high carbonα-olefins was prospected,which can provide a reference for the development of novel catalysts for CO_(2) hydrogenation to high carbonα-olefins.
作者 李自琴 王康洲 高新华 马清祥 赵天生 张建利 LI Ziqin;WANG Kangzhou;GAO Xinhua;MA Qingxiang;ZHAO Tiansheng;ZHANG Jianli(State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering,College of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,Ningxia,China;School of Materials and New Energy,Ningxia University,Yinchuan 750021,Ningxia,China)
出处 《低碳化学与化工》 CAS 北大核心 2023年第3期11-21,共11页 Low-Carbon Chemistry and Chemical Engineering
基金 国家自然科学基金(21965029) 宁夏自然科学基金重点项目(2022AAC02002)。
关键词 CO_(2)加氢 Fe基催化剂 高碳α-烯烃 构效关系 反应机理 CO_(2) hydrogenation Fe-based catalysts high carbonα-olefins structure-activity relationship reaction mechanism
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  • 1Shuwei Chen Zhangfeng Qin Ailing Sun Jianguo Wang.Theoretical and Experimental Study on Reaction Coupling: Dehydrogenation of Ethylbenzene in the Presence of Carbon Dioxide[J].Journal of Natural Gas Chemistry,2006,15(1):11-20. 被引量:5
  • 2Piotr Michorczyk,Jan Ogonowski.Dehydrogenation of propane in the presence of carbon dioxide over oxide-based catalysts[J]. Reaction Kinetics and Catalysis Letters . 2003 (1)
  • 3Ching-Shiun Chen,Wu-Hsun Cheng.Study on the Mechanism of CO Formation in Reverse Water Gas Shift Reaction Over Cu/SiO2 Catalyst by Pulse Reaction, TPD and TPR[J]. Catalysis Letters . 2002 (3-4)
  • 4K. R. P. M. Rao,F. E. Huggins,V. Mahajan,G. P. Huffman,V. U. S. Rao,B. L. Bhatt,D. B. Bukur,B. H. Davis,R. J. O’Brien.M?ssbauer spectroscopy study of iron-based catalysts used in Fischer-Tropsch synthesis[J]. Topics in Catalysis . 1995 (1-4)
  • 5Sun Ailing,Qin Zhangfeng,Wang Jianguo.Reaction cou-pling of ethylbenzene dehydrogenation with water-gas shift. Applied Catalysis . 2002
  • 6Deng Shuang,Li Songgeng,Li Huiquan,et al.Oxidativedehydrogenation of ethane to ethylene with CO2over Fe-Cr/ZrO2catalysts. Industrial&Engineering ChemistryResearch . 2009
  • 7Joo O-S,Jung K-D,MoonI,et al.Carbon dioxide hydrogen-ation to form methanol via a reverse-water-gas-shift reaction (the CAMEREprocess). Industrial&Engineering Chem-istry Research . 1999
  • 8Rethwisch D G,Dumesic J A.Adsorptive and catalytic prop-erties of supported metal oxides:III.Water-gas shift oversupported iron and zinc oxides. Journal of Catalysis . 1986
  • 9Ginés MJ L,Marchi AJ,Apesteguía C R.Kinetic study ofthe reverse water-gas shift reaction over CuO/ZnO/Al2O3catalysts. Applied Catalysis . 1997
  • 10Goguet A,Meunier F C,Tibiletti D,et al.Spectrokineticin-vestigation of reverse water-gas-shift reaction intermediatesover a Pt/CeO2catalyst. The Journal of Physical Chemis-try B . 2004

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