芳烃与烷烃化合物参与的光化学与电化学硼化反应

Photochemical and Electrochemical Borylation Involving Aryl and Alkyl Compounds

有机硼化合物是重要的有机合成砌块,并被广泛应用于材料与医药领域.发展实用、简洁的硼化反应合成有机硼化合物一直是有机硼化学的核心课题之一.近年来,光化学和电化学硼化反应取得了快速发展,已成为合成有机硼化合物的重要方法.从能量来源及反应底物类型的角度出发,总结了芳烃与烷烃化合物参与的光化学、电化学和光电化学硼化反应的研究进展,同时也对今后光化学与电化学硼化反应的发展方向进行了展望.

Organoboron compounds are important building blocks in organic synthesis and have been widely applied in materials and pharmaceutical science.The development of practical and concise borylation reactions to synthesize organoboron compounds has always been one of the core topics of organoboron chemistry.Recently,photochemical and electrochemical borylation reactions have gained rapid development and emerged as important methods towards the synthesis of organoboron compounds.The recent research progress concerning photochemical,electrochemical and photoelectrochemical borylation involving aryl and alkyl compounds from the view of energy resources and substrates is reviewed.Additionally,research trends of this area are also discussed.