摘要
电极材料是电氧化技术的核心关键。碳基材料具有稳定性好、结构可调、导电性佳、来源广泛等优势。从碳基材料电氧化过程出发,简要描述了碳材料在阳极电流下的降解行为及其可复合活性材料增强自由基产生能力。重点综述了碳纳米管、石墨烯、生物质碳为代表的碳基材料通过缺陷调控、表面修饰、界面工程等方式调控电氧化性能的研究进展,最后对发展碳基阳极材料提出展望。
Electrode materials are the key to electro-oxidation technology.Carbon-based materials have the advantages of good stability,adjustable structure,good conductivity,and wide range of sources.Starting from the electrooxidation process of carbon-based materials,this article briefly introduces the degradation behavior of carbon materials under anode current and their ability to enhance free radical generation by composite active materials.The research progress of carbon based materials,such as carbon nanotubes,graphene,and biomass carbon,in regulating the electrooxidation performance through defect control,surface modification,and interface engineering is systematically reviewed.Finally,the development of carbon-based anode materials is prospected.
作者
郭旭
张永政
夏厚兵
杨娜
朱真珍
齐晶瑶
GUO Xu;ZHANG Yongzheng;XIA Houbing;YANG Na;ZHU Zhenzhen;QI Jingyao(Biomass Energy Development and Utilization National and Local Joint Engineering Research Center,Harbin Institute of Technology,Harbin 150006,Heilongjiang,China;School of Environment,Harbin Institute of Technology,Harbin 150006,Heilongjiang,China;School of Chemistry and Chemical Engineering,Harbin Institute of Technology,Harbin 150006,Heilongjiang,China;College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science&Technology,Xi’an 710021,Shaanxi,China)
出处
《化工学报》
EI
CSCD
北大核心
2023年第5期1862-1874,共13页
CIESC Journal
基金
生物质能源开发利用国家地方联合工程研究中心面上项目(2021B001)
中央高校基本科研业务费专项资金项目(HIT_NSRIF202216)。
关键词
电化学
催化剂
电氧化
碳基材料
水处理
electrochemistry
catalyst
electrooxidation
carbon-based materials
water treatment
