Magnetic ordering induced magnetodielectric effect in Ho_(2)Cu_(2)O_(5) and Yb_(2)Cu_(2)O_(5)

Materials with strongly coupled magnetic and electronic degrees of freedom provide new possibilities for practical applications.In this paper,we have investigated the structure,magnetic property,and magnetodielectric(MD) effect in Ho_(2)Cu_(2)O_(5) and Yb_(2)Cu_(2)O_(5) poly crystalline samples,which possess a non-centrosymmetric polar structure with space group Pna2_(1).In Ho_(2)Cu_(2)O_(5),Ho^(3+) and Cu^(2+) sublattices order simultaneously,exhibiting a typical paramagnetic to antiferromagnetic transition at 13.1 K.While for Yb_(2)Cu_(2)O_(5),two magnetic transitions which originate from the orderings of Yb^(3+)(7.8 K) and Cu^(2+)(13.5 K) sublattices are observed.A magnetic field induced metamagnetic transition is obtained in these two cuprates below Neel temperature(T_(N)).By means of dielectric measurement,distinct MD effect is demonstrated by the dielectric anomaly at T_(N.)Meanwhile,the MD effect is found to be directly related to the metamagnetic transition.Due to the specific spin configuration and different spin evolution in the magnetic field,a positive MD effect is formed in Ho_(2)Cu_(2)O_(5),and a negative one is observed in Yb_(2)Cu_(2)O_(5).The spontaneous dielectric anomaly at T_(N) is regarded as arising from the shifts in optical phonon frequencies,and the magnetoelectric coupling is used to interpret the magnetic field induced MD effect.Moreover,an H-T phase diagram is constructed for Ho_(2)Cu_(2)O_(5) and Yb_(2)Cu_(2)O_(5) based on the results of isothermal magnetic and dielectric hysteresis loops.