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A cucurbit[8]uril-stabilized 3D charge transfer supramolecular polymer with a remarkable confinement effect for enhanced photocatalytic proton reduction and thioether oxidation

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摘要 A highly water-soluble tetrahedral compound T1 that contains one tetraphenylmethane core and four 2-oxynaphthelene-CH_(2)-4,4’-bipyridinium(NP-CH_(2)-DIPY)side arms has been prepared.Control experi-ments reveal that NP-CH_(2)-BIPY undergoes antiparallel dimerization which is stabilized by two charge transfer interactions with NP as an electron-rich donor and BIPY as an electron-deficient acceptor.
出处 《Organic Chemistry Frontiers》 SCIE EI 2022年第5期1327-1335,共9页 有机化学前沿(英文)
基金 We are grateful to the National Natural Science Foundation of China(Project No.21921003,21890730 and 21890732)for the financial support of this work.
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