摘要
It is of significance to prepare biodegradable electromagnetic interference(EMI)shielding materials with high EMI shielding effectiveness(SE)in order to solve electromagnetic and environmental pollution problems.In this paper,environmentally friendly EMI shielding silver nanowires(AgNWs)/poly(L-lactic acid)(PLLA)/poly(D-lactic acid)(PDLA)/ferroferric oxide(Fe_(3)O_(4))composites with step-wise asymmetric structures were prepared by a facile one-step non-solvent-induced phase separation method.The conductive AgNW network was constructed at a low mass fraction of 5 wt.%on the surface of stereo-complexed crystalline poly(lactic acid)(SC-PLA)film(1.08×10^(4) S/m).Moreover,magnetic Fe_(3)O_(4)is mainly distributed in the skeleton of porous SC-PLA film.Due to the synergistic effect of AgNWs and Fe_(3)O_(4),the EMI SE of SC-PLA films reaches up to 50.3 dB.Interestingly,SC-PLA film modified with triethoxy-1H,1H,2H,2H-tridecafluoro-n-octylsilane(TTO)demonstrates an outstanding water contact angle of about 150.2°compared with the pure PLLA film(134.7°),stemming from the synergistic effect of denser SC-PLA nano-protrusions and low-surface-energy TTO.Thus,we successfully fabricated the high EMI shielding SC-PLA film with wonderful superhydrophobicity,which extends the application performance and service life of portable electronics in moist environments.
基金
This work was supported by the National Natural Science Foundation of China(Nos.52263003 and 51963003)
the Guizhou Provincial Science and Technology Projects(Nos.[2020]1Z044 and ZK[2022]Maj019).
