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Stereocomplexed Materials of Chiral Polymers Tuned by Crystallization:A Case Study on Poly(lactic acid)

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摘要 CONSPECTUS:Widespread in chemistry and biochemistry,chirality strongly affects the biological,chemical,material,and physical properties.As a downstream derivative,the enantiopure polymers of opposite chirality can cocrystallize in the stereocomplex(SC)in their enantiomeric blends or block copolymers,which endows the materials with improved physical properties and specific functions such as enhanced melting temperature,thermal stability,crystallizability,and hydrolytic resistance.
出处 《Accounts of Materials Research》 2022年第12期1309-1322,共14页 材料研究述评(英文)
基金 support of the National Natural Science Foundation of China(22073083 and 21873083).
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