摘要
能源是人类赖以生存的基本保障。C_(1)化学转化作为能源领域的重要反应,为人类社会发展提供了一定的保障。随着“双碳”目标的提出,节能减排,环境友好成为C_(1)催化转化研究者们的新追求。最近,光驱动C_(1)化学转化以其温和条件可以实现C_(1)小分子向多种高附加值产物转化引起了研究者们的关注。水滑石由于其独特的层状二维结构在光驱动C_(1)化学转化中得到了广泛应用。本文分别从水滑石前体作为催化剂、水滑石基衍生物作为催化剂和水滑石作为催化剂载体三个方面综述了纳米态水滑石基光驱动C_(1)化学转化的最新研究进展,并总结该领域未来的挑战。希望通过对上述研究工作的分析与讨论,为研究人员在光驱动C_(1)化学领域提供一定的启示。
Energy is the basic guarantee for human survival.As an important reaction in field of energy,C_(1)chemical conversion has safeguarded the development of human society.With the proposal of"double carbon"goal,energy saving-emission reduction and environmental friendliness have been the new pursuit of C_(1)catalytic conversion researchers.Recently,photo-driven C_(1)chemical conversion has attracted researchers’attention through which C_(1)small molecules can be transformed into various value-added products under ambient condition.Layered double hydroxides(LDH)have gained wide application in photo-driven C_(1)chemical conversion for their distinctive two-dimensional layered structure.Herein,we review the latest progress achieved in nano-state LDH based materials for photo-driven C_(1)chemical conversion from three aspects containing LDH precursors acting as catalyst,LDH derivatives acting as catalyst and LDH acting as catalyst carrier,and conclude the challenges this field may face in the future.Through analyzing and discussing above-mentioned work,we hope to offer researchers some inspiration on photo-driven C_(1)chemistry.
作者
段驰
李振华
张铁锐
Chi Duan;Zhenhua Li;Tierui Zhang(Key Laboratory of Photochemical Conversion and Optoelectronic Materials,Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China)
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2023年第6期940-953,共14页
Progress in Chemistry
基金
国家自然科学基金项目(No.51825205,52120105002,22088102,22209190)
中国博士后基金项目(No.2021M703288,2022T150665)资助。
