钳形氮杂环卡宾金属络合物的研究进展

Research Progress on Pincer N-Heterocyclic Carbene Metal Complexes

氮杂环卡宾作为一类结构和性质特殊且便于调控的新型配体,近年来备受研究者关注.结构多样、性能各异的多种氮杂环卡宾金属络合物也被广泛合成,并被应用于催化、合成、材料、医药等领域.综述了近年来含N、P、S、O、Se等杂原子配位及不同杂化态C的钳形氮杂环卡宾金属络合物的合成及应用研究进展.

As a type of novel ligands featuring special structure and properties that can be easily regulated,N-heterocyclic carbenes(NHCs)have attracted much research attention in recent years.Various NHC metal complexes with typical structure and properties have been synthesized and utilized widely in the fields of catalysis,synthesis,materials,pharmaceuticals,etc.Here,recent research progress on the synthesis and applications of pincer NHC metal complexes containing heteroatoms of N,P,S,O,Se,etc.and C featuring different hybrid state is summarized.