摘要
A novel series of polybenzazoles with rigid-rod benzoxazole cycle and soft methylene segment was designed and synthesized via solution condensation poly-merizations from 4,6-diamino-l,3-benzenediol dipho-sphate,terephthalic acid and aliphatic dicarboxylic acid.The structures of polybenzazoles were characterized by means of FT-IR,1H NMR and Wide-angle X-ray diffrac-tion(WAXRD).All the polymers show excellent thermal stability and the TdS was above 471℃,The intrinsic vis-cosities[η]of the polymers ranged from 0.8 to 0.9.The UV-Vis absorption peaks of the polymers in MSA were blue-shifted from 429 nm for PBO to 291 nm for PBOC7,and the Stokes shifts in PL spectra enlarged.
