摘要
Through inverted-design rather than modifying the generally-assumed S active sites in popular MoS_(2),we unlock the potential of Mo sites and successfully prepared novel MoS_(2)@Ni_(3)S_(2)/NF core-shell nanospheres as a catalyst for the high-performance hydrogen evolution reaction(HER).TheΔGH at the Mo site is optimized via Ni_(3)S_(2)to achieve excellent HER activity.At low current densities,it has similar activity to the Pt/C.However,its performance is better than Pt/C at high density.Moreover,our catalyst shows a considerable stability at a variety of current densities for 50 h,promising to substitute noble metal catalysts in application of commercial alkaline electrocatalysts.
基金
supported by the National Natural Science Foundation of China(grant Nos.51872115,52101256)
the Project funded by China Postdoctoral Science Foundation(grant No.2020M680043)
Science and Technology Research Project of the Department of Educationof JilinProvince(grant No.JKH20211083KJ)
2020 INTERNATIONAL COOPERATION Project of the Department of Science and Technology of Jjilin Province(grant No.20200801001GH).
