摘要
金属有机框架(MOF)是金属和有机配体组成的多孔材料,具有比表面积大、孔隙率高、催化效率强、稳定性好等优点,成为了改善储能器件性能的首选材料之一。MOF材料分为3大类:原始MOF、MOF复合材料及MOF衍生物材料。其中,MOF复合材料和MOF衍生物材料又有许多小分类:MOF金属氧化物、MOF金属硫化物、MOF硒化物、碳基MOF及双金属MOF等,根据各自的特点分别用于不同的储能器件中。综述了MOF材料应用于锂离子电池(LIBs)、锂硫电池(LSBs)、钠离子电池(SIBs)、超级电容器(SCs)以及其他储能器件中的现状,并对未来MOF材料在储能器件中的应用进行了展望。
Metal-organic frameworks(MOF)is a novel type of materials composed of metal and organic ligands.It possesses the advantages of large specific surface area,high porosity,strong catalytic efficiency and superior stability,has become one of the preferred materials to improve the performance of energy storage devices.MOF materials are divided into three categories:pristine MOF,MOF composites and MOF derivatives.Moreover,MOF composite materials and MOF derivatives can be divided into MOF metal oxides,MOF metal sulfides,MOF selenides,carbon-based MOFs and bimetallic MOFs,which are introduced in different energy storage devices according to their respective properties.The development of MOF materials for advanced lithium ion batteries(LIBs),lithium sulfur batteries(LSBs),sodium ion batteries(SIBs),supercapacitors(SCs)and other energy storage devices is summarized.Finally,the future application and prospect of MOF materials in energy storage devices is envisioned.
作者
李傲
王飞
黄荣威
游丹
张义永
李雪
张英杰
LI Ao;WANG Fei;HUANG Rong-wei;YOU Dan;ZHANG Yi-yong;LI Xue;ZHANG Ying-jie(School of Materials Science and Engineering,Kunming University of Science and Technology,Kunming 650093,China;School of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Kunming 650093,China;National Local Joint Engineering Research Center for Lithium-ion Batteries and Materials Preparation Technology,Kunming University of Science and Technology,Kunming 650093,China)
出处
《化学试剂》
CAS
北大核心
2023年第9期61-69,共9页
Chemical Reagents
基金
云南自然科学基金:云南省重点研发计划项目(202103AA080019)
云南省重大科技项目(202202AG050003)
云南省基础研究项目(202101BE07001-018)。
