金属有机配位聚合物在催化领域中的应用

Application of Metal-organic Coordination Polymers in Catalysis

金属有机配位聚合物因其结构的可变性、可调节性及其在光催化与电催化等方面的应用优势而备受关注。介绍了催化性金属有机配位聚合物的材料结构特点,即丰富的表面活性位点和高活性中心的固有活性。分析了其催化氧化机制,包括金属活性位点、活性官能团、孔通道效应等。探讨了合成策略:约束效应的内部优化与修正,链接器安装。未来,需寻找价格低廉、通用性强、合成方法温和的配体,以促进金属有机配位聚合物材料的广泛应用。

Metal-organic coordination polymers have attracted much attention due to their structural variability,adjustability and advantages in photocatalysis and electrocatalysis.The study introduces the material structure characteristics of catalytic organometallic coordination polymers,i.e.the abundant surface active sites and the inherent activity of high active centers;analyzes the catalytic oxidation mechanism,including metal active sites,active functional groups and pore channel effects;and explores the synthesis strategy:internal optimization and correction of constraint effect,and linker installation.In the future,it is necessary to search for ligands with low price,strong versatility and mild synthesis methods to promote the wide application of metal-organic coordination polymer materials.