摘要
A novel coordination polymer,formulated as Zn_(6)(TIB)_(4)(BPTC)_(3)(DMA)_(4)(H_(2)O)_(10)[TIB=1,3,5-tris(1-imidazolyl)-benzene,H_(4)BPTC=3,3',5,5'-biphenyltetracarboxylate],has been synthesized and structurally characterized.Further investigations reveal that it presents a new topology(topological symbol{6^(2).8^(4)}{6^(3)}4{6^(5).8}6{6^(6)}2)based on self-penetration,and shows interesting fluorescent properties.
基金
We are thankful for financial support from the 973 Program(Nos.2014CB932101,2013CB933200)
the National Natural Science Foundation of China(Nos.21471148,21141006)
the Natural Science Foundation of Fujian Province(No.2011J05038).
