摘要
A chiral[M_(3)L_(3)]^(6+)-type nanobowl reported here was self-assembled from cis-protected mono-palladium com-plex[(RRdiph)Pd](NO_(3))_(2)(where RRdiph=(1R,2R)-(+)-1,2-diphenylethylenediamine)as chiral corners and 4,7-phenanthroline ligand(L)as linkers in aqueous media.The hydrophobic cavity-containing metallo-macrocycle[Pd_(3)L_(3)]^(6+)·6NO_(3)(1)with a syn,syn,syn orientation has been characterized by 1H NMR spectroscopy,elemental analysis,CD spectra and X-ray diffraction determination.
基金
supported by National Natural Sci-ence Foundation of China (Nos.91127039,51073171)
Beijing Natural Science Foundation (No.2112018)
the Research Funds of Renmin University of China (No.11XNL011)
BSRF (Beijing Synchrotron Radiation Facility)for the crystal structure determination using synchrotron radiation X-ray diffraction analysis.
