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低介质损耗增韧剂的合成及应用研究

Synthesis and application of low dielectric loss toughening agents
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摘要 本文设计合成了一种新型低介质损耗增韧剂(Si-DABPA),并对其结构进行表征,研究了其对马来酰亚胺(DFE950)的增韧效果。结果表明:Si-DABPA和二烯丙基双酚A(DABPA)对DFE950具有相同的反应活性,与DFE950/DABPA固化物相比,DFE950/Si-DABPA固化物的耐热降解性提高,10 GHz下介电常数(Dk)和介质损耗因数(Df)有所降低。与DFE950/DABPA/PPE固化物相比,DFE950/Si-DABPA/PPE固化物的拉伸强度提高,而弯曲强度和冲击强度变化不大。 A novel low dielectric loss toughening agent(Si-DABPA)was designed and synthesized,and its structure was characterized,then its toughening effect on bismaleimide(DFE950)was studied.The results show that the Si-DABPA and diallyl bisphenol A(DABPA)have the same reactivity to DFE950.Compared with the DFE950/DABPA cured material,the Thermal degradation resistance of the DFE950/Si-DABPA cured material increases,and the dielectric constant(Dk)and dielectric loss factor(Df)decrease at 10 GHz.Compared with the DFE950/DABPA/PPE cured material,the tensile strenght of the DFE950/Si-DABPA/PPE cured material increases,while the bending strength and impact strength change little.
作者 李成武 邹静 周友 唐安斌 马寒冰 LI Chengwu;ZOU Jing;ZHOU You;TANG Anbin;MA Hanbing(School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621000,China;National Insulating Material Engineering Research Center,Sichuan EM Technology Co.,Ltd.,Mianyang 621000,China)
出处 《绝缘材料》 CAS 北大核心 2023年第9期38-42,共5页 Insulating Materials
关键词 马来酰亚胺 二烯丙基双酚A 介质损耗因数 增韧剂 maleimide diallyl bisphenol A dielectric loss factor toughening agents
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