摘要
设计合成一种基于Keggin型多酸的无机-有机杂化配合物,利用水热原位合成法获得[SiW_(12)O_(40)][Ag(bpy)_(2)]4·H_(2)O(1),(bpy=2,2′-联吡啶).该配合物中的bpy由2,2′-联吡啶-6,6′-二羧酸原位脱羧得到.利用单晶X射线衍射、元素分析、红外光谱及热重分析对该配合物的结构进行表征,并研究其荧光、光催化降解有机染料、电化学性质及抑菌性能.
We designed and synthesized an inorganic-organic hybrid complex based on Keggin-type polyacids,and obtained[SiW_(12)O_(40)][Ag(bpy)_(2)]4·H_(2)O(1)(bpy=2,2′-bipyridine)by using hydrothermal in situ synthesis method.The bpy in complex 1 was obtained by in situ decarboxylation of 2,2′-bipyridine-6,6′-dicarboxylic acid.The structure of complex was characterized by single crystal X-ray diffraction,elemental analysis,infrared spectrum and thermogravimetric analysis,and its fluorescence,photocatalytic degradation of organic dyes,electrochemical and antibacterial properties were studied.
作者
王亮
徐廷双
耿嘉琦
杨博琦
齐翀
于晓洋
陆通
WANG Liang;XU Tingshuang;GENG Jiaqi;YANG Boqi;QI Chong;YU Xiaoyang;LU Tong(College of Chemistry,Jilin University,Changchun 130012,China;Institute of Translational Medicine,the First Hospital of Jilin University,Changchun 130021,China;Institute of Chemistry and Pharmaceutical Engineering,Jilin Institute of Chemical Technology,Jilin 132022,Jilin Province,China)
出处
《吉林大学学报（理学版）》
CAS
北大核心
2023年第5期1223-1229,共7页
Journal of Jilin University:Science Edition
基金
国家自然科学基金(批准号:22271116).
关键词
Keggin型多酸
水热合成
结构表征
电化学性质
Keggin-type polyacid
hydrothermal synthesis
structural characterization
electrochemical property
