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HFO-1243zf爆燃特性实验研究

Experimental study on the flammability of HFO-1243zf
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摘要 3,3,3-三氟丙烯(HFO-1243zf)是一种热物性适宜、环境友好的新一代人工合成类制冷剂。然而在规模化应用前,其基础燃爆特性必须被探明。参考ASHRE 34标准和ISO—817标准方法,分别实测了HFO-1243zf的可燃极限范围与高浓度下的燃烧速度。结果显示:HFO-1243zf的可燃极限范围为4.45%±0.05%~15.8%±0.2%(浓度),并且随环境温度的升高而扩大,随环境湿度的升高而略微缩减。HFO-1243zf的燃烧速度随等效比的增大呈先逐渐增大,在达到极大值后又逐渐减小的现象。 3,3,3-Trifluoropropene(HFO-1243zf)is a kind of synthetic environmentally friendly refrigerants that has applicable thermophysical property.The flammability of HFO-1243zf should be ascertained before extending its usage.The flammability limits and burning velocity of HFO-1243zf are tested as per the ASHRAE 34 and ISO—817 standards,respectively.The tested flammability limit range is 4.45%±0.05%~15.8%±0.2%in volume fraction,which is enlarged with the increase of the environmental temperature but slightly lessened with the increase of relative humidity.The burning velocity of HFO-1243zf is increased by increasing the equivalence ratio,until which increases to a peak value and then gradually decreases on a further increase of the fuel concentration.
作者 吴曦 区祖迪 张鑫杰 徐士鸣 朱晓静 WU Xi;OU Zudi;ZHANG Xinjie;XU Shiming;ZHU Xiaojing(Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education,School of Energy and Power Engineering,Dalian University of Technology,Dalian 116024,Liaoning,China)
出处 《化工学报》 EI CSCD 北大核心 2023年第S01期346-352,共7页 CIESC Journal
基金 国家自然科学基金项目(52076026) 中央高校基本科研业务费专项资金项目(DUT22JC25,DUT22QN255)。
关键词 制冷剂 氟代烯烃 R1243zf 可燃性 燃烧速度 refrigerant hydrofluoroolefin R1243zf flammability burning velocity
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