摘要
The separator is a key component of sodium-ion battery,which greatly affects the electrochemical performances and safety characteristics of the battery.Conventional glass fiber separator cannot meet the requirements of large-scale application because of high cost and poor mechanical properties.Herein,the novel composite separators are prepared by a simple slurry sieving process using glass fiber separator scraps and ordinary qualitative filter paper as raw materials.As the composite mass ratio is 1:1,the composite separator has excellent comprehensive properties,including tensile strength of 15.8 MPa,porosity of 74.3%,ionic conductivity of 1.57×10^(-3)S·cm^(-1)and thermal stability at 210℃.The assembled sodium-ion battery shows superior cycling performance(capacity retention of 94.1%after 500 cycles at 1C)and rate capacity(retention rate of 87.3%at 10C),and it maintains fine interface stability.The above results provide some new ideas for the separator design of high-performance and low-cost sodium-ion batteries.
基金
financially supported by the National Natural Science Foundation of China (Nos.52002106,22262013,and 52102261)
the Talent Project of Anhui Provincial Department of Education (Nos.gxyqZD2021127 and gxbjZ D2022050)
the Natural Science Foundation of Anhui Province,China (Nos.2108085QB68,2208085QB34,and2022AH052157)
the Research Funds for Hefei Normal University (Nos.14098100 and 2021cyxy061)。