摘要
As the cross-coupling needs of chemists continue to grow for accessing increasingly complex targets,radical-based transformations have become mainstay methodologies for the discovery of new reactivity under mild and wastelimiting conditions.En route to such methodological advancements,the observation of the 1,2-boron shift a novel radical rearrangement in its application has generated a new cross-coupling methodology to access products that were previously inaccessible or otherwise cumbersome to make.The origins of this radical rearrangement along with the synthetic applications to organic chemistry are highlighted.
