多组分有机框架化合物的合成及表征

Synthesis and Characterization of Multicomponent Organic Framework Compounds

文章利用苯并咪唑(BiB)和氯冉酸(CA)作为配体,通过与[Cp^(*)RhCl_(2)]_(2)反应得到双核化合物[Cp^(*)_(2)Rh_(2)(μ-BiB)]Cl_(2)和[Cp^(*)_(2)Rh_(2)(μ-CA)]Cl_(2),并通过分步配位合成法,合成了一系列四核、六核的有机金属环状和三棱柱状化合物。此外,通过引入客体分子蒽和三亚苯与主体结构发生D-A作用和π-π堆积作用,分别得到了相应的主客体有机金属化合物。

In this paper,the binuclear compounds [Cp^(*)_(2)Rh_(2)(μ-BiB)]Cl_(2) and [Cp^(*)_(2)Rh_(2)(μ-CA)]Cl_(2) were synthesized by using benzimidazole(BiB) and chloranilic acid(CA) as ligand by reaction with [Cp^(*)RhCl_(2)]_(2).A series of organometallic ring and three pyramid compounds with four and six nuclei have been synthesized by stepwise coordination method.In addition,by introducing the guest molecule anthracene and triphenylene into the main structure with D-A and π-π stacking,the corresponding host-guest organometallic compounds were obtained respectively.